研究成果
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有机功能材料研究室研究成果


Selected Publications:

2017

[2] Sun C., Zhao X., Wang P., Wang H., Han. B. Thiophene-basedconjugated microporous   polymers: synthesis, characterization and efficient gas st orage. Sci China Chem.,  2017, 60.

[1] Li L, Li B, Li C, Ma Z, Xu L, Wang H. Selective deprotonation of tetra[3,4]thienylene in the presence of n-BuLi. Org. Chem. Front., 2017, 4: 1019-1023.

2016

[10] Zhang S, Liu X, Li C, Li L, Song J, Shi J, Morton M, Rajca S, Rajca A, Wang H. Thiophene-Based Double Helices: Syntheses, X-ray Structures, and Chiroptical Properties. J. Am. Chem. Soc., 2016, 138(31): 10002-10010. (Highlighted by SYNFACTS 12(10), 1036, 2016.)

[9] Zhou Y, Li M, Guo Y, Lu H, Song J, Bo Z, Wang H. Dibenzopyran-Based Wide Band Gap Conjugated Copolymers: Structural Design and Application for Polymer Solar Cells. ACS Appl. Mater. & Interfaces, 2016, 8(45): 31348-31358.

[8] Li M, Liu L, Zhao C, Zhou Y, Guo Y, Song J, Wang H. Side chain engineering of dithienosilole-based polymers for application in polymer solar cells. Dyes and Pigments, 2016, 134: 480-486.

[7] Dai H, Yi W, Deng K, Wang H, Zeng Q. Formation of Coronene Clusters in Concentration and Temperature Controlled Two-Dimensional Porous Network. ACS Appl. Mater. & Interfaces, 2016, 8(32): 21095-21100.

[6] Liu Q, Gao X, Zhong H, Song J, Wang H. Planar Heptathienoacenes Based on Unsymmetric Dithieno[3,2-b:3′,4′-d]thiophene: Synthesis and Photophysical Properties. J. Org. Chem., 2016, 81(18): 8612-8616. (Highlighted by SYNFACTS 12(11), 1149, 2016.)

[5] Sun C-J, Wang P-F, Wang H, Han B-H. All-thiophene-based conjugated porous organic polymers, Polym. Chem., 2016, 7(31): 5031-5038.

[4] Zhao X, Zhang L, Song J, Kan Y, Wang H. Naphthotetrathiophene-Based Helicene-Like Molecules: Synthesis and Photophysical Properties. J. Org. Chem., 2016, 81(11): 4856-4860.

[3] Liu L, Zhang L, Li M, Guo Y, Song J, Wang H. Random dithienosilole-based terpolymers: Synthesis and application in polymer solar cells. Dyes and Pigments, 2016, 130: 63-69.

[2] Liu L, Song J, Lu H, Wang H, Bo Z. Novel dithienosilole-based conjugated copolymers and their application in bulk heterojunction solar cells. Polym. Chem., 2016, 7: 319-329.

[1] Li L, Zhao C, Wang H. Recent Progress in Synthesis and Application of Thiophene Oligomers Based on Bithiophene Dicarbanions. Chemical Record (Review), 2016, 16(2): 797-809.

2015

[6] Song J, Guo Y, Liu L, Wang H. Efficient synthesis of dibenzopyran building block and its application in organic photovoltaics. Dyes and Pigments, 2015, 122: 184-191.

[5] Li C, Wu L, Xu W, Song J, Shi J, Yu P, Kan Y, Wang H. Silicon Spiro Double Helicene-like Compounds Based on Dithieno[2,3-b:3′,2′-d]thiophene: Syntheses and Crystal Structures. J. Org. Chem., 2015, 80(21): 11156-11161. (Highlighted by SYNFACTS 12(2), 0144, 2016.)

[4] Yi W, Zhao S, Sun H, Kan Y, Shi J, Wan S, Li C, Wang H. Isomers of organic semiconductors based on dithienothiophenes: the effect of sulphur atoms positions on the intermolecular interactions and field-effect performances, J. Mater. Chem. C, 2015, 3(41): 10856-10861.

[3] Xu L, Wang P-F, Zhang J-J, Wu W, Shi J-W, Yuan J-F, Han H, Wang H. Synthesis and spectroscopic properties of propeller type 2,4,6-tri(anthracen-9-yl)-1,3,5-triazine, RSC-Advances, 2015, 5(64): 51745-51749.

[2] Song J, Wu T, Zhao X, Kan Y, Wang H. Synthesis and molecular properties of butterfly-shaped tetrathiophene derivatives. Tetrahedron, 2015, 71(12): 1838-1843.

[1] Zhao C, Xu L, Wang Y, Li C, Wang H. Recent Progress in the Synthesis and Application of Saddle-shaped Cyclooctatetrathiophenes and Their Derivatives. Chinese Journal of Chemistry, 2015, 33(1): 71-78.

2014

[4] Shi J, Zhao W, Xu L, Kan Y, Li C, Song J, Wang H. Small Molecules of Cyclopentadithiophene Derivatives: Effect of Sulfur Atom Position and Substituted Groups on Their UV–Abs Properties. J. Phys. Chem. C, 2014, 118(15): 7844-7855.

[3] Wang Y, Song J, Xu L, Kan Y, Shi J, Wang H. Synthesis and Characterization of Cyclooctatetrathiophenes with Different Connection Sequences. J. Org. Chem., 2014, 79(5): 2255-2262.

[2] Li C, Zhang Y, Zhang S, Shi J, Kan Y, Wang H. From N,N-diphenyl-N-naphtho[2,1-b]thieno[2,3-b:3′,2′-d]dithiophene-5-yl-amine to propeller-shaped N,N,N-tri(naphtho[2,1-b]thieno[2,3-b:3′,2′-d]dithiophene-5-yl)-amine: syntheses and structures. Tetrahedron, 2014, 70(25): 3909-3914.

[1] Wang Y, Gao D, Shi J, Kan Y, Song J, Li C, Wang H. Derivation of saddle shaped cyclooctatetrathiophene: increasing conjugation and fabricating pentamer. Tetrahedron, 2014, 70(3): 631-636.

2013

[8] Liu X, Yu P, Xu L, Yang J, Shi J, Wang Z, Cheng Y, Wang H. Synthesis for the Mesomer and Racemate of Thiophene-Based Double Helicene under Irradiation. J. Org. Chem., 2013, 78(12): 6316-6321.

[7] Sun H, Shi J, Zhang Z, Zhang S, Liang Z, Wan S, Cheng Y, Wang H. Synthesis and Structure of Bull’s Horn-Shaped Oligothienoacene with Seven Fused Thiophene Rings. J. Org. Chem., 2013, 78(12): 6271-6275.

[6] Han H, Zhao W, Song J, Li C, Wang H. Selectivity of Br/Li Exchange and Deprotonation of 4,4′-Dibromo-3,3′-bithiophene for Synthesis of Symmetrical and Unsymmetrical Dithienoheteroaromatic Rings. J. Org. Chem., 2013, 78(6): 2726-2730.

[5] Wu T, Shi J, Li C, Song J, Xu L, Wang H. Synthesis of Dendrimers Based on Tetrakis(thiophene-2-yl)ethene as New Dendron. Org. Lett., 2013, 15(2): 354-357.

[4] Shi J, Xu L, Li Y, Jia M, Kan Y, Wang H. Intermolecular interactions in organic semiconductors based on annelated β-oligothiophenes and their effect on the performance of organic field-effect transistors. Organic Electronics, 2013, 14(3): 934-941.

[3] Wang Z, Putta A, Mottishaw J D, Wei Q, Wang H, Sun H. Molecular Origin of Isomerization Effects on Solid State Structures and Optoelectronic Properties: A Comparative Case Study of Isomerically Pure Dicyanomethylene Substituted Fused Dithiophenes. J. Phys. Chem. C, 2013, 117(33): 16759-16768.

[2] Zhong H, Shi J, Kang J, Wang S, Liu X, Wang H. Ring-opening reaction of 2,5-dioctyldithieno[2,3- <i>b</i> :3',2'- <i>d</i> ]thiophene in the presence of aryllithium reagents. Beilstein J. Org. Chem., 2013, 9: 767-774.

[1]Wang Z, Shi J, Tian X, Xu L, Li C, Wang H. Syntheses and Crystal Structures of 2,7-Di(trimethylsilyl)thieno[3,2-e]benzothiophene, 1,2,5,6(5)-Tetra(trimethylsilyl)-1,2,5,6(2,3)-tetrathiophenacyclooctaphan-3(z),7(z)-diene, and 2,7-Di(trimethylsilyl)thieno[3,2-e]benzothiophene-4-ol. J. Heterocycl. Chem., 2013, 50(5): 1021-1024.

2012

[3] Zhao J, Qiu D, Shi J, Wang H. Synthesis of Dithieno[2,3-b:4′,3′-d]siloles and Their Selective Bromination. J. Org. Chem., 2012, 77(6): 2929-2934.  (Highlighted by SYNFACTS 8(6), 0621, 2012 and ChemInform 43(28), S0060, 2012)

[2] Yang J, Li C, Wang Z, Wang H. Syntheses of Fused Thiophenes:[7]Helicene and Double Helicene Bearing Chiral Alkyl Chains. Lett. Org. Chem., 2012, 9(10): 706-710.

[1] Li Z, Li C, Zhao C, Wu W, Wang H. Spectroscopic study on the intermolecular double proton transfer in 4-(naphthalen-1-yl)-6-octyl-1,3,5-triazin-2-amine with acid. J. Lumin., 2012, 132(10): 2794-2798.

2011

[5] Shi J, Li Y, Jia M, Xu L, Wang H. Organic semiconductors based on annelated β-oligothiophenes and its application for organic field-effect transistors, J. Mater. Chem., 2011, 21(44): 17612-17614.

[4] Zhao C, Xu L, Shi J, Li C, Wang Z, Wang H. The Ring-Opening Reaction of 7,7’-Dimethyl-2, 5-bis(trimethylsilyl)-dithieno[2,3-b:3’,2’-d]silole in the Presence of NXS (X = Cl, Br, I). Int. J. Org. Chem., 2011, 01(04): 162-166.

[3] Zhao C, Shi J, Li C, Wang H. Efficient Synthesis of Substituted Dithieno[2,3-b:3',2'-d]siloles and A 10-Membered Silicon-Bridged Thiophene-Based Cyclophane. Lett. Org. Chem., 2011, 8(10): 728-731.

[2] Shi J, Wang H, Wang H, Tian H, Geng Y, Yan D. Improve on/off ratio of organic heterojunction transistors by adopting single-sandwich configuration. Solid-State Electronics, 2011, 61(1): 65-68.

[1] Cai Y-Q, Wu W, Wang H, Miyake J, Qian D-J. Monolayers and Langmuir–Blodgett films of luminescent 1,3,5-triazine derivatives containing naphthalene or anthracene chromophores. Surface Science, 2011, 605(3–4): 321-327.

2010 and before

[18] Wang Z, Shi J, Wang J, Li C, Tian X, Cheng Y, Wang H. Syntheses and Crystal Structures of Benzohexathia[7]helicene and Naphthalene Cored Double Helicene. Org. Lett., 2010, 12(3): 456-459. (Highlighted by SYNFACTS (4), 0411, 2010)

[17] Wang Z, Zhao C, Zhao D, Li C, Zhang J, Wang H. The preparation of substituted bithiophenyl aldehydes via the ring opening of dithieno[2,3-b:3′,2′-d]thiophene in the presence of n-BuLi. Tetrahedron, 2010, 66(12): 2168-2174.

[16] Wang Z, Shi J, Li C, Zhao D, Wang Z, Wang H. The Synthesis of Octyl-Substituted Hexathia[7]heterohelicene Based on dithieno[2,3-b:3',2'-d]thiophene via Irradiation. Lett. Org. Chem., 2010, 7(1): 85-89.

[15] Wang D, Jiang X, Zhao C, Wang Z, Wang H, Du Z. Study on the micro-region structure and properties of two dithienothiophene-dicarboxylic acids. Chinese Sci. Bull., 2010, 55(6): 478-483.

[14] Zhu Y, Liu H, Li F, Ruan Q, Wang H, Fujiwara M, Wang L, Lu G Q. Dipolar Molecules as Impellers Achieving Electric-Field-Stimulated Release. J. Am. Chem. Soc., 2010, 132(5): 1450-1451.

[13] Li C, Shi J, Xu L, Wang Y, Cheng Y, Wang H. Syntheses and Crystal Structures of Fused Thiophenes: [7]Helicene and Double Helicene, a D2-Symmetric Dimer of 3,3′-Bis(dithieno[2,3-b:3′,2′-d]thiophene). J. Org. Chem., 2009, 74(1): 408-411.

[12] Wu W, Xu L, Shi J, Qin X, Wang H. “One-Pot” Reaction Involving Ring Formation of Silole, Thiophene Ring-Opening Alkynylation, and S−S Coupling. Organometallics, 2009, 28(6): 1961-1964.

[11] Wang H, Wang Z, Zhu S, Shi J. The efficient synthesis of dibenzo[d,d’]benzo[1,2-b:4,3-b’]dithiophene and cyclopenta[1,2-b:4,3-b’]bis(benzo[d]thiophen)-6-one. Beilstein J. Org. Chem., 2009, 5.

[10] Xu L, Wang Z, Xu K, Shi J, Wang H. The Efficient Synthesis of Dithieno[3,4-b:3',4'-d]thiophene. Lett. Org. Chem., 2009, 6(6): 474-477.

[9] Xiao S, Pink M, Wang H, Rajca S, Rajca A. Chiral tetrathienylene: synthesis and X-ray structure. J. Sulfur Chem., 2008, 29(3-4): 425-432.

[8] Wang Y, Wang Z, Zhao D, Wang Z, Cheng Y, Wang H. Efficient Synthesis of Trimethylsilyl-Substituted Dithieno[2,3-b:3′,2′-d]thiophene, Tetra[2,3-thienylene] and Hexa[2,3-thienylene] from Substituted [3,3′]Bithiophenyl. Synlett, 2007: 2390-2394.

[7] Rajca A, Miyasaka M, Pink M, Wang H, Rajca S. Helically Annelated and Cross-Conjugated Oligothiophenes:  Asymmetric Synthesis, Resolution, and Characterization of a Carbon−Sulfur [7]Helicene. J. Am. Chem. Soc., 2004, 126(46): 15211-15222.

[6] Rajca A, Pink M, Rojsajjakul T, Lu K, Wang H, Rajca S. X-ray Crystallography and Magnetic Studies of a Stable Macrocyclic Tetranitroxide. Intramolecular Dimer of Nitroxides in a Constrained Geometry of the Upper Rim of Calix[4]arene. J. Am. Chem. Soc., 2003, 125(28): 8534-8538.

[5] Freedman T B, Cao X, Rajca A, Wang H, Nafie L A. Determination of Absolute Configuration in Molecules with Chiral Axes by Vibrational Circular Dichroism:  A C2-Symmetric Annelated Heptathiophene and a D2-Symmetric Dimer of 1,1‘-Binaphthyl. J.Phys. Chem. A, 2003, 107(39): 7692-7696.

[4] Shenhar R, Wang H, Hoffman R E, Frish L, Avram L, Willner I, Rajca A, Rabinovitz M. Self-Assembled, Helically Stacked Anionic Aggregates of 2,5,8,11-Tetra-tert-butylcycloocta[1,2,3,4-def;5,6,7,8-d‘e‘f‘]bisbiphenylene, Stabilized by Electrostatic Interactions. J. Am. Chem. Soc., 2002, 124(17): 4685-4692.

[3] Rajca A, Wang H, Bolshov P, Rajca S. A Greek cross dodecaphenylene: sparteine-mediated asymmetric synthesis of chiral D2-symmetric π-conjugated tetra-o-phenylenes. Tetrahedron, 2001, 57(17): 3725-3735.

[2] Rajca A, Wang H, Pawitranon V, Brett T J, Stezowski J J. Synthesis and structure of tetrathiophene with a chiral 1,1′-binaphthyl kink, Chem. Commun., 2001, (12): 1060-1061.

[1] Rajca A, Wang H, Pink M, Rajca S. Annelated Heptathiophene: A Fragment of a Carbon–Sulfur Helix. Angew. Chem. Int. Ed., 2000, 112(24): 4655-4657.



Chinese Patents:

[10]发明名称: “一种非对称二噻吩并噻咯衍生物的合成方法”,史建武、王华、赵金灿、李春丽.专利号: ZL201210003661.0, 授权公告日期: 2016.03.30

[9]发明名称: “非对称二噻吩并芳杂环化合物的合成方法,王华、韩辉、宋金生、李春丽、史建武、赵文玲. 专利号: ZL201310043495.1, 授权公告日期: 2016.02.17

[8]发明名称: “通过二噻吩并噻咯卤代开环反应制备二甲硅醇基卤代联噻吩的方法,徐莉、王华、李春丽、赵彩云.专利号: ZL201110154695.5, 授权公告日期: 2016.01.13

[7]发明名称: “二噻吩并[2,3-b:2',3'-d]噻吩的制备方法,王华、孙会靓、刘新明、李春丽、万世胜. 专利号: ZL 201310151508.7, 授权公告日期: 2015.07.15

[6]发明名称: “一种对称的含二硫键化合物的制备方法”, 王华、田新勇、王治华、李春丽、吴伟、徐莉、史建武. 专利号: ZL 200910064127.9, 授权公告日期: 2012.08.15

[5]发明名称: “一种均三嗪衍生物及该衍生物的制备方法及该衍生物在对胸腺嘧啶识别中的应用”, 发明人: 王华、李宗耀、赵春梅、李春丽、吴伟. 专利号: ZL 200910064841.8, 授权公告日期: 2012.05.30

[4]发明名称: “二噻吩并[3,4-b:3',4',-d]噻吩的制备方法”, 王华、王振、徐莉、李宗耀、徐坤、史建武、王治华、李春丽. 专利号: ZL 200910064380.4, 授权公告日期: 2011.06.15

[3]发明名称: “2-烷基蒽衍生物的制备方法”, 王华、赵春梅、徐莉. 专利号: ZL 200710054810.5, 授权公告日期: 2011.06.08

[2]发明名称: “一种噻吩大环化合物及其衍生物的制备方法”, 王华、王阳光、王志华、徐莉、王永. 专利号: ZL 200710054833.6, 授权公告日期: 2010.12.29

[1]发明名称: “二噻吩并[2,3-b:3',2',-d]噻吩的制备方法”, 王华、王阳光、王振、王志华、赵东锋、赵春梅. 专利号: ZL 200710054834.0, 授权公告日期: 2010.12.1